The UEFA Champions League is in Matchday 3 and one of the matches schedule for Tuesday, Oct. 21 has Paris Saint-Germain battling Bayer Leverkusen.

Barcelona, PSG, Arsenal and Manchester City are all in action when the Champions League resumes on Tuesday night.

The UEFA Champions League league phase is back, as 36 teams will play eight matches — four home and four away — in bids to reach the knockout rounds.There are two paths to the Round of 16: Eight teams will qualify directly via the league phase table, while eight more will emerge from playoff ties pitting teams 9-24 in home-and-away legs.MORE — UEFA Champions League 2025-26 hub — Fixtures, dates, scoresAnd there's no set path for greatness, something we learned from the first edition of the tournament's new structure.Runners-up Inter Milan earned a bye as the fourth-seed last league phase, but champions Paris Saint-Germain finished 15th and did not have their playoff status secured until Matchday 7.UEFA Champions League 2025-26 league phase table — StandingsTeams 1-8 qualify for knockout roundsTeams 9-24 qualify for playoff round — two-legged tiesTeams 25-36 eliminated from EuropeParis Saint-Germain — 3-0-0, +10 GD, 9 pointsInter Milan — 3-0-0, +9 GD, 9 pointsArsenal — 3-0-0, +8 GD, 9 pointsBorussia Dortmund — 2-1-0, +5 GD, 7 pointsManchester City — 2-1-0, +4 GD, 7 pointsBayern Munich — 2-0-0, +6 GD, 6 pointsNewcastle United — 2-0-1, +6 GD, 6 pointsReal Madrid — 2-0-0, +6 GD, 6 pointsBarcelona — 2-0-1, +5 GD, 6 pointsQarabag — 2-0-0, +3 GD, 6 pointsPSV Eindhoven — 1-1-1, +2 GD, 4 pointsTottenham Hotspur — 1-1-0, +1 GD, 4 pointsMarseille — 1-0-1, +3 GD, 3 pointsClub Brugge — 1-0-1, +2 GD, 3 pointsSporting CP — 1-0-1, +2 GD, 3 pointsEintracht Frankfurt — 1-0-1, 0 GD, 3 pointsLiverpool — 1-0-1, 0 GD, 3 pointsAtletico Madrid — 1-0-1, -1 GD, 3 pointsChelsea — 1-0-1, -1 GD, 3 pointsGalatasaray — 1-0-1, -3 GD, 3 pointsAtalanta — 1-0-1, -3 GD, 3 pointsNapoli — 1-0-1, -5 GD, 3 pointsUnion Saint-Gilloise — 1-0-1, -6 GD, 3 pointsJuventus — 0-2-0, 0 GD, 2 pointsBodo/Glimt 0-2-0, 0 GD, 2 pointsPafos — 0-2-1, -4 GD, 2 pointsBayer Leverkusen — 0-2-1, -5 GD, 2 pointsAS Monaco — 0-0-1, -3 GD, 1 pointSlavia Prague — 0-1-1, -3 GD, 1 pointVillarreal — 0-2-1, -3 GD, 1 pointsCopenhagen — 0-1-2, -4 GD, 1 pointOlympiacos — 0-1-2, -7 GD, 1 pointKairat Almaty — 0-1-2, -8 GD, 1 pointBenfica — 0-0-3, -5 GD, 0 pointsAthletic Bilbao — 0-0-2, -5 GD, 0 pointsAjax — 0-0-2, -6 GD, 0 points

This soccer match is scheduled to start at 3 p.m. EDT and will be broadcast on Paramount+. Fans looking to watch this match can do so for free by using Paramount+, which offers a free trial and has exclusive access to the UEFA Champions League, UEFA Europa League and UEFA Conference League along with NWSL action.

Here’s how to watch the Champions League match on TV and live stream as well as the latest team news. The Sporting News takes you through all the information you need to follow the game.

Villarreal is in the Champions League for the first time since the 2021-22 season, as the team finished fifth in La Liga last year. Villarreal is looking for its first win, having lost to Tottenham Hotspur and drawn with Juventus. These two teams met in the group stage of the 2011-12 UCL season, with ManCity winning both matches.

Erling Haaland scored again as Manchester City defeated Villarreal 2-0 in the UEFA Champions League on October 21, though injury concerns mount for Pep Guardiola ahead of upcoming fixtures

Barcelona takes on Olympiacos at the Estadi Olímpic Lluís Companys on Tuesday, Oct. 21. Kickoff is set for 6:45 p.m. CET local time in Spain, making it a 12:45 p.m. ET or 9:45 a.m. PT start in the US, a 5:45 p.m. BST kickoff in the UK, and a 3:45 a.m. AEDT start in Australia on Wednesday.